- Production of [...]
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A method for producing alkenyl isocyanurate by reacting cyanuric acid or isocyanuric acid with an unsaturated alcohol while in the presence of a palladium-loaded-activated-carbon catalyst. (Unsaturated alcohol example) R1-5: H, C1-20 alkyl, C6-20 aryl, C6-20 heterocyclic hydrocarbon; n: 1-4 (2-propen-1-ol, 3-buten-1-ol, 4-penten-1-ol, 5-hexen-1-ol, 2-buten-1-ol, 3-penten-2-ol, 2-methyl-2-propen-1-ol, and the like). (Example of palladium-loaded-activated-carbon catalyst) A zero-valent metal palladium, a bivalent palladium compound, or a catalyst obtained by loading activated carbon with these mixtures.
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Paragraph 0019; 0021; 0023-0025; 0030; 0033; 0036
(2018/12/12)
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- INTER- AND INTRAMOLECULAR REARRANGEMENTS OF CYANURIC ACID TRIALLYL ESTERS
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It is shown that the catalytic and thermal rearrangements of cyanuric acid triallyl esters to isocyanuric acid esters proceed via inter- and intramolecular mechanisms.Cross-reaction products are formed when the reaction is carried out with a mixture of homologs, while the reaction in the presence of a hydroxy-containing compound gives its allyl ether and diallyl isocyanurate.
- Likhterov, V. R.,Klenovich, S. V.,Etlis, V. S.,Tsareva, L. A.,Pomerantseva, E. G.,Shmuilovich, S. M.
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p. 308 - 311
(2007/10/02)
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