Pd-catalyzed allylative dearomatisation using Grignard reagents
Pd-catalyzed allylative dearomatisation of naphthyl halides is shown to be feasible by employing Grignard reagents. The high reactivity of the nucleophile allows for fast reactions and low catalyst loading, while a plethora of successfully substituted compounds illustrate the broad scope. Five membered heteroaromatic compounds are also demonstrated to be reactive under similar conditions.
Boldrini, Cosimo,Harutyunyan, Syuzanna R.
p. 11807 - 11810
(2021/11/30)
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