Synthesis of 2-Aryl-(2-R)-arsenines by Cyclohexadienol -> Arsabenzene Rearrangement
KOH/crown-6 phase-transfer catalyzed addition of arylarsines (phenylarsine, p-tolylarsine) to the (3-R)-3-methoxy-1,4-pentadiynes 13 yields the cis/trans isomeric 1-aryl-1,4-dihydro-(4-R)-4-methoxyarsenines, the 1H-NMR- and 13C-NMR spectra of which ar
Maerkl, Gottfried,Liebl, Rainer,Baier, Horst
p. 1610 - 1632
(2007/10/02)
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