Studies on UV/Vis Absorption Spectra of Azo Dyes. XVIII. Substituent Effects on the Absorption Maxima of the n-->?* and ?-->?* Bands of 4-N,N-Diethylaminoazobenzenes
The spectra of 27 substituted 4-N,N-diethylaminoazobenzenes are determined.The band system can be separated by deconvolution into two Gaussian curves.The results so obtained show that the effects of substituents on n-->?* and ?-->?* transitions are similar and that electron withdrawing substituents in the phenylazo residue cause a bathochromic shift of both the n-->?* and the ?-->?* bands.
Haessner, Carmen,Mustroph, H.
p. 493 - 498
(2007/10/02)
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