Polymeric dicarbonyl ruthenium(I) acetate - An efficient catalyst for alkene cyclopropanation with diazoacetates
The polymeric complex [Ru2(CO)4(μ-OAc)2](n) is the first Ru(I) catalyst that efficiently catalyzes cyclopropanation of alkenes with diazoacetic esters. The related dinuclear catalyst Ru2(CO)4(μ-OAc)2(MeCN)2 shows a similar performance only for cyclopropanation of monosubstituted alkenes.
Maas,Werle,Alt,Mayer
p. 881 - 888
(2007/10/02)
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