- Triphendioxazine dyestuffs
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The novel triphendioxazine dyestuffs of the formula STR1 in which the substituents R, R', T1, T2, X, Y and n have the meanings given in the description are highly suitable for the dyeing and printing of cellulose-containing or amido-containing material.
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- Process for the preparation of aminobenzenesulfonic acids
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There is disclosed a process for the preparation of compounds of formula STR1 wherein the symbols are as defined in claim 1, which process comprises dissolving a compound of formula STR2 in sulfuric acid, adding this solution to oleum and reacting the mixture in the temperature range from 10° to 80° C. until a sulfo group has been completely introduced, and, in an optional further step, subjecting the reaction mixture to further reaction in the temperature range from 100° to 200° C. to introduce a second sulfo group. The compounds of formula (1) obtainable by this process are useful intermediates for the synthesis of dyes and are particularly suitable diazo components for the synthesis of azo dyes.
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- Amino disazo dyestuffs containing a fluoropyrimidinyl or a fluorotriazinyl reactive group
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Dyestuffs of the formula STR1 wherein X=--CH=CH2, --CH2 --CH2 OSO3 H, --CH=CHCl or --CH2 --CH2 Cl and Y=a fiber-reactive fluoropyrimidinyl or fluorotriazine radical and wherein u and v=H or SO3 H, where u~v. Such dyestuffs suitable for dyeing and printing diverse substrates, particularly cotton, to give products a high degree of dyestuff fixation.
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- 2,4-diamino-6-fluorotriazine disazo reactive dyestuffs
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A dyestuff of the formula STR1 in which R is H or Ch3 STR2 in which R1 is H, substituted or unsubstituted C1 -C4 -alkyl or --X--Y X is a divalent aliphatic, cycloaliphatic, aliphaticcycloaliphatic radical or an araliphatic radical Y is COOH, SO3 H, OSO3 H or SO2 G, in which G is CH=CH2 or --CH2 --CH2 --Z, in which Z denotes a group which can be eliminated under alkaline conditions, R2 is H or C1 -C4 -alkyl, and the benzene radical D and the benzene or naphthalene radical L can contain customary substituents, is suitable for the dyeing and printing of OH- and NH-containing materials. They produce lightfast and wetfast brilliant dyeings and prints.
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- Alkanol substituted disazo orange dye for nylon
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The specification describes a new group of alkanol substituted disazo compounds that are useful in dyeing polyamide textile fibers in orange hues. The new compounds are compatible with several acid blue dyes and several acid red dyes that are commercially important as dyes for nylon. The new compounds are particularly well suited for use as the "yellow" component in trichromatic systems for dying polyamide carpeting and other textiles. The new compounds are relatively inexpensive to make and have outstanding application and fastness properties. Other aspects of the specification are concerned with a method of making the new compounds and with a method of dyeing polyamides with said compounds and to the novel dyed polyamides resulting from the use of the new group of compounds as dyes.
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- Azo reactive dyestuffs having an aryl-triazinyl-aryl diazo component
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Optionally metallized azo dyestuffs which in the form of the free acid correspond to the formula STR1 wherein K is the radical of a benzene, naphthalene, pyrazolone, pyridone, pyrimidone, acetoacetic acid arylide or aminopyrazole coupling component; A is a non-ionic substituent; X is STR2 wherein W is a direct bond or a bridge member to a C atom of the benzene or naphthalene nucleus or the coupling component K; R is hydrogen or C1 -C4 -alkyl; B is a direct bond or a bridge member, especially -CO- or -SO2 -, to a C atom of Q; Q is a reactive radical; m is 0, 1 or 2; n is 0, 1 or 2; p is 0 or 1; q is 0, 1 or 2; and r is 0 or 1; and their use for the dyeing and printing of natural and regenerated cellulose fibre materials such as cotton and rayon, as well as natural and synthetic polyamide fibre materials, for example those of wool, silk, poly-ε-caprolactam or polycondensate of hexamethylene-diamine and adipic acid. The dyeings obtained, espeically those on cotton and rayon, are distinguished by good fastness properties, especially fastness to wet processing and to light.
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- Process for monoacylating water-soluble organic amino compounds
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A process for the monoacylation of water-soluble organic amino compounds with 2,4,6-trifluoro-s-triazine, which comprises introducing all reactants simultaneously and continuously in the amounts necessary for the required throughput into the reaction space and removing the resultant reaction products continuously therefrom.
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