Studies in sesquiterpenes-lx reversion of longipinane to himachalane system: Revision of structure of isocentdarol
Longipinene on exposure to acids rapidly rearranges to furnish α- and β-himachalenes, longifolene and isolongifolene. Longipinene epoxide, under acid catalysis, gives several products resulting from fragmentation and Wagner-Meerwein rearrangement. All products have been fully characterised. Formation of isocentdarol in this reaction requires revision of its stereochemistry at the centre carrying tertiary hydroxyl function.
Shastri, Mayank H.,Dev, Sukh
p. 4905 - 4918
(2007/10/02)
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