Catalytic oxidative cleavage of olefins promoted by osmium tetroxide and hydrogen peroxide
Hydrogen peroxide was employed as the terminal oxidant in the osmium tetroxide mediated oxidative cleavage of olefins, producing the corresponding aldehyde and ketone products. Aryl olefins are cleaved in good to excellent yield regardless of arene electronics. Alkyl olefins cleave in moderate to good yield for di- and tri-substituted alkenes. The Royal Society of Chemistry 2011.
Hart, Stewart R.,Whitehead, Daniel C.,Travis, Benjamin R.,Borhan, Babak
experimental part
p. 4741 - 4744
(2011/08/06)
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