- Deprotonation of 1,1-diboronic esters and reactions of the carbanions with alkyl halides and carbonyl compounds
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The efficient deprotonation of 1,1-diboronic esters has been accomplished with lithium 2,2,6,6-tetramethylpiperidide in the presence of tetramethylethylenediamine in tetrahydrofuran. Bis(l,3,2-dioxaborin-2-yl)methane, (C3H6O2/s
- Matteson, Donald S.,Moody, Robert J.
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- Carbanlons from α-phenylthio boronic esters as synthetic intermediates
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(Phenylthio)methaneboronic acid (1) was easily prepared from (phenylthio)methyllithium and trimethyl borate and was converted to boronic esters 2.
- Matteson, Donald S.,Arne, Karl H.
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p. 280 - 288
(2008/10/08)
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