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6636-22-2

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Organocatalytic Enantioselective Addition of α-Aminoalkyl Radicals to Isoquinolines
With a dual organocatalytic system involving a chiral phosphoric acid and a dicyanopyrazine-derived chromophore (DPZ) photosensitizer and under the irradiation with visible light, an enantioselective Minisci-type addition of α-amino acid-derived redox-active esters (RAEs) to isoquinolines has been developed. A variety of prochiral α-aminoalkyl radicals generated from RAEs were successfully introduced on isoquinolines, providing a range of valuable α-isoquinoline-substituted chiral secondary amines in high yields with good to excellent enantioselectivities.
Liu, Xiangyuan,Liu, Yang,Chai, Guobi,Qiao, Baokun,Zhao, Xiaowei,Jiang, Zhiyong
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p. 6298 - 6301
(2018/10/09)

Mechanism of nasal absorption of drugs II: Absorption of L-tyrosine and the effect of structural modification on its absorption
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Huang,Kimura,Bawarshi-Nassar,Hussain
p. 1298 - 1301
(2007/10/02)

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Chemical Properties

Boiling Point: 385.8°C at 760 mmHg
Flash Point:187.1°C
Density: 1.275g/cm³
Solubility:Aqueous Acid (Slightly, Sonicated), DMSO (Slightly)
Storage Temp.:Store at 0-5°C
Vapor Pressure: 1.21E-06mmHg at 25°C
PSA: 89.62000
LogP: 1.26660

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