Synthesis of Stereoisomeric Medium-Ring α,α′-Dihydroxy Cycloalkanones
The stereochemical course of the epoxidation of the silyl enol ethers of 2-tert-butyldimethylsilyl-oxycycloheptanone and -cyclooctanone has been investigated and shown to proceed exclusively anti to the existing α-substituent. 2-(Benzyloxy)cyclooctanone b
Paquette, Leo A.,Hartung, Ryan E.,Hofferberth, John E.,Vilotijevic, Ivan,Yang, Jiong
Chemical consequences of the ground-state conformations of cyclooctyl rings. Examples of reactivity differences in α-hydroxy and α,α′-dihydroxy eight-membered cyclic ketones
A program directed toward the elucidation of various conformational factors that control reactivity differences in cyclooctyl and cyclooctenyl systems is described. This overview reports on the divergent reactivity observed in the alkylation of saturated
Paquette, Leo A.,Hartung, Ryan
p. 1201 - 1208
(2007/10/03)
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