Conversion of Carbon-Sulfur Linkages into Carbon-Silicon Ones via Reductive Silylation. Preparation of Silyl Enol Ethers of Acyltrimethylsilanes
Reductive cleavage of carbon-sulfur linkages of silyl enol ethers of thiocarboxylic S-esters can be induced by treatment with sodium or potassium-sodium alloy in the presence of chlorotrimethylsilane, and the corresponding silyl enol ethers of acyltrimethylsilanes can be prepared in high yields.
Kuwajima, Isao,Mori, Akio,Kato, Masahiro
p. 2634 - 2638
(2007/10/02)
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