One-carbon homologation of N-sulfonylaziridines to allylic amines using dimethylsulfonium methylide
(Chemical Equation Presented) Regio- and stereodefined allylic N-sulfonylamines are synthesized in high yields and under experimentally straightforward conditions by reaction of N-sulfonylaziridines with excess dimethylsulfonium methylide.
Hodgson, David M.,Fleming, Matthew J.,Stanway, Steven J.