New and improved methods for the conversion of nitroalkanes into geminal chloronitroso compounds
The scope and limitations of a new method for the preparation of geminal chloronitroso compounds involving treatment of a nitronate anion with oxalyl chloride are described in full, and a milder, high yielding, and more chemoselective variant using the de
Bou-Moreno, Rafael,Luengo-Arratta, Sandra,Pons, Valerie,Motherwell, William B.
p. 6 - 12
(2013/03/13)
Observations on the reaction of nitronate anions with oxalyl chloride: A new method for the preparation of geminal chloronitroso compounds
A simple method for the preparation of geminal chloronitroso compounds from secondary nitro compounds via their derived nitronate anions is presented.
Bou-Moreno, Rafael,Luengo-Arratta, Sandra,Motherwell, William B.
supporting information; experimental part
p. 2097 - 2099
(2011/05/09)
Generation of nitryl chloride from chlorotrimethylsilane-acetyl nitrate reaction: A one-pot preparation of gem-chloronitro compounds from oximes
While iso-amyl nitrite reacts with chlorotrimethylsilane to give NOCl, iso-amyl nitrate does not yield NO 2Cl with silicon reagent. However, acetyl nitrate reacts successfully with chlorotrimethylsilane to give nitryl chloride, which is charact
Mohammed, Abdulkarim H. A.,Nagendrappa, Gopalpur
experimental part
p. 571 - 577
(2010/12/20)
N,N′-Dichloro bis(2,4,6-trichlorophenyl)urea (CC-2): an efficient reagent for the synthesis of α-chloro-nitroso compounds
A simple, efficient, rapid, and mild method for the synthesis of α-chloro-nitroso compounds is described using bis(2,4,6-trichlorophenyl)urea (CC-2).