- Organosilane compound and organosilica obtained therefrom
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Provided is an organosilane compound expressed by any one of the following general formulae (1) to (7): (wherein: Ar represents a phenylene group or the like; R1 represents a hydrogen atom or the like; R2 to R8 each represent a methyl group or the like; n represents an integer in a range from 0 to 2; m represents an integer of 1 or 2; L represents a single bond or the like; X represents a hydrogen atom or the like; and Y represents a hydrogen atom or the like).
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Page/Page column 13-14
(2008/12/07)
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- Preparation of functionalized aryl(diallyl)ethoxysilanes and their palladium-catalyzed coupling reactions giving sol-gel precursors
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A series of molecular building blocks containing allylsilyl groups, which can be incorporated into the appropriate sol-gel precursors as fragments, were prepared. The allylsilyl group is retained unchanged over the course of all reactions giving sol-gel precursors and behave as the synthetic equivalent of alkoxysilyl groups toward sol-gel polymerization, but are stable enough to allow purification by silica gel chromatography. These allylsilanes were successfully used as building blocks to construct functional sol-gel precursors via palladium-catalyzed coupling reactions.
- Maegawa, Yoshifumi,Nagano, Toyohiro,Yabuno, Tatsuya,Nakagawa, Hiroki,Shimada, Toyoshi
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p. 11467 - 11474
(2008/03/12)
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- Improved synthesis of aryltriethoxysilanes via palladium(O)-catalyzed silylation of aryl iodides and bromides with triethoxysilane
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The scope of the palladium-catalyzed silylation of aryl halides with triethoxysilane has been expanded to include aryl bromides. A more general Pd(0) catalyst/ligand system has been developed that activates bromides and iodides: palladium(O) dibenzylideneacetone (Pd(dba)2) is activated with 2-(di-tert-butylphosphino)biphenyl (Buchwald's ligand) (1:2 mol ratio of Pd/phosphine). Electronrich para- and meta-substituted aryl halides (including unprotected aniline and phenol derivatives) undergo silylation to form the corresponding aryltriethoxysilane in fair to excellent yield; however, ortho-substituted aryl halides failed to be silylated.
- Manoso,DeShong
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p. 7449 - 7455
(2007/10/03)
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- Diamino compounds and their production method
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The present invention is to provide diamino compounds useful to polyamide raw materials for production of liquid crystal alignment layers having excellent voltage holding ratios without development of image-sticking phenomena, a method for producing the compounds and liquid crystal display devices equipping the liquid crystal alignment layers. The Diamino compounds are represented by the general formula (1): STR1 wherein R indicates hydrogen or an alkyl group having 1 to 8 carbon atoms, further, X, Y and Z indicate hydrogen, an alkyl group having 1 to 3 carbon atoms or fluorine, respectively, and a part or all of them may be the same or different, and the positions of these substitutive groups may be ortho positions or meta positions.
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