The Effect of Lewis Acid and Solvent on Concerted 1,2-Acyl Migration
Lewis acid catalyzed 1,2-benzoyl migration in (E)- and (Z)-1,3-diphenyl-2-buten-1-on oxides (dypnone oxides) is a concerted process that occurs with inversion of configuration at the migration terminus when nonpolar solvents are employed.In methanol solve
Bach, Robert D.,Domagala, John M.
p. 4181 - 4188
(2007/10/02)
Thermal Rearrangement of trans-2,3-Epoxy-1,3-diphenylbutan-1-one. A Concerted 1,2-Carbonyl Migration
The thermal rearrangement of a chiral α,β-epoxyketone is a concerted process that proceeds without loss of optical activity and with inversion of configuration at the migration terminus.
Bach, Robert D.,Domagala, John M.
p. 1472 - 1474
(2007/10/02)
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