Total synthesis of (+)-19-deoxyicetexone, (-)-Lcetexone, and (+)-5-epi-icetexone
The first asymmetric total syntheses of 19-deoxylcetexone, Icetexone, and 5-epl-Icetexone was achieved from eplmerlc tricyclic dlenes.
Majetlch, George,Grove, Jeremy L.
supporting information; experimental part
p. 2904 - 2907
(2009/12/06)
Expedient syntheses of espintanol, p-methoxycarvacrol and thymoquinol dimethyl ether
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Soederberg, Bjoern C.,Fields, Shari L.
p. 221 - 225
(2007/10/03)
Bromination of phenols using an algal bromoperoxidase
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Shang Meiling,Okuda,Worthen
p. 307 - 310
(2007/10/02)
Effects of Halogen Substiution on Reactions of o-Quinol Acetates with Isopropylmagnesium Bromide and Diisopropylmagnesium. Competition between Unimolecular Decomposition and Bimolecular Reactions of Radical Anions
When a single methyl substituent at C-2 or C-4 of an o-quinol acetate (1) is replaced by a halogen atom, a greatly decreased yield of the corresponding 3-isopropylphenol is obtained from reaction of 1 with isopropylmagnesium bromide.Replacement of a second methyl group by halogen results in a marked increase in the yield of the 3-isopropylphenol.Essentially identical product distributions are obtained from reactions of halogenated o-quinol acetates with concentrated and dilute Grignard solutions and with diisopropylmagnesium, in contrast to reactions with halogen-free o-quinol acetates.Reactions with hexadeuterioisopropylmagnesium bromide gave reduction products bearing increasing percentages of deuterium at C-3 as the number of bromines on the rings of the ω-quinol acetates increased.These data are consistent with reactions of halogenated o-quinol acetates, in contrast to those of halogen-free analogues, proceeding solely by SET processes.The reactions of halogen-stabilized radical anions with isopropyl radicals compete with decomposition of radical anions to phenoxy radicals.
Miller, Bernard,Haggerty, John G.
p. 174 - 179
(2007/10/02)
Reactions of Halogenated o-Quinol Acetates with Isopropylmagnesium Bromide and Di-isopropylmagnesium. Mechanism for Formation of Ethers, Reduction Products, and m-Isopropylphenols
A mechanism is proposed to account for the nature and the variations in yields of products from reactions of Grignard reagents with halogenated o-quinol acetates.
Miller, Bernard,Haggerty, John G.
p. 1617 - 1619
(2007/10/02)
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