cas 71027-02-6, 4,4,4-TRIFLUOROCROTONIC ACID | Articles data ｜lookchem

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71027-02-6

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PRODUCTION METHOD OF FLUORINE-CONTAINING UNSATURATED CARBOXYLIC ACID
PROBLEM TO BE SOLVED: To provide a production method of a compound of formula (4), that is, a fluorine-containing unsaturated carboxylic acid, which is industrially preferable, economical, and environmentally friendly. SOLUTION: A production method of a compound of formula (4) includes subjecting a compound of formula (3) to a reaction in the presence of a base (here Rf is a 1-4C perfluoroalkyl). SELECTED DRAWING: None COPYRIGHT: (C)2021,JPO&INPIT
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Paragraph 0293-0302

(2021/02/11)

BICYCLIC JAK INHIBITORS AND USES THEREOF
Provided herein are compounds of Formulas (I), (II), (III), and (IV) and subformulas thereof, wherein the variables are defined herein. Also provided herein are pharmaceutical compositions comprising a compound of Formula (I), (II), (III), or (IV) and methods of using the compounds, e.g., in the treatment of immune disorders, inflammatory disorders, and cancer.
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Paragraph 000308

(2020/10/20)

The effect of fluoromethyl groups on the diastereoselectivity in the electrophilic alkylation
The effect of fluoromethyl groups on the diastereoselectivity in the electrophilic alkylation is described. In particular, the electrophilic alkylation of enolates with a trifluoromethyl group was proceeded with highly diastereofacial selectivity based on the steric and/or electrostatic effect of substituent with strong electron withdrawing.
Tamura, Kenji,Yamazaki, Takashi,Kitazume, Tomoya,Kubota, Toshio
p. 918 - 930
(2007/10/03)

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Chemical Properties

Melting Point: 55-56°C
Boiling Point: 68-69°C 20mm
Flash Point:>110oC
Density: 1.411g/cm3
Vapor Pressure: 0.0959mmHg at 25°C
PKA: pK1:3.15 (25°C)
PSA: 37.30000
LogP: 1.18950

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