Polar Effects in Free-radical Reactions; Reductive Alkylation of Olefins Conjugated with Electron-withdrawing Groups: Kinetics and Mechanism
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Citterio, Attilio,Minisci, Francesco,Serravalle, Marco
p. 2174 - 2189
(2007/10/02)
Process for preparing bifunctional aliphatic organic compounds
This invention consists of a process for preparing bifunctional aliphatic organic compounds of at least 6 carbon atoms, wherein a cycloaliphatic oxyhydroperoxide is reacted with an alpha-olefine having its double bond activated by a conjugate electron-attracting group, in the presence of a bivalent Cr salt, a bivalent V salt or a trivalent Ti salt.
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(2008/06/13)
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