REACTIONS OF BROMOTRIFLUOROMETHANE AND RELATED HALIDES PART VII CONDENSATIONS WITH THIOCYANATES AND ISOCYANATES IN THE PRESENCE OF ZINC
Reaction of zinc and bromotriflouromethane, or perfluroalkyliodides, with thiocyanates and isocyanates gives respectively trifluromethylsulfides and substituted trifluroacetamides, as well as their long chain analogs.
Tordeux, M.,Francese, C.,Wakselman, C.
p. 27 - 34
(2007/10/02)
ETHYL PENTAFLUOROPROPANETHIOATE: A USEFUL PENTAFLUOROPROPIONYLATING AGENT FOR AMINES AND ALCOHOLS
Ethyl pentafluoropropanethioate, prepared by treating ethanethiol with hexafluoro-1,2-epoxypropane in the presence of triethylamine, was found to be a convenient pentafluoropropionylating agent for amines and alcohols.