Formyloxyacetoxyphenylmethane and 1,1-diacylals as versatile O-formylating and O-acylating reagents for alcohols
Formyloxyacetoxyphenylmethane, symmetric 1,1-diacylals and mixed 1-pivaloxy-1-acyloxy-1-phenylmethanes have been used as moisture stable O-formylating and O-acylating reagents for primary and secondary alcohols, allylic alcohols and phenols under solvent/catalyst free conditions to afford their corresponding esters in good yield.
Chapman, Robert S.L.,Francis, Molly,Lawrence, Ruth,Tibbetts, Joshua D.,Bull, Steven D.
p. 6442 - 6452
(2018/10/02)
Synthese von (-)-Spathulenol
In reference to the famous synthesis of (-)-aromadendrene, the synthesis of (-)-spathulenol (31) and (-)-7-epi-spathulenol (32) from (-)-β-pinene via (-)-perillaaldehyde and the intermediates 7, 19 and 25 is described.
Surburg, Horst,Mondon, Albert
p. 118 - 131
(2007/10/02)
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