SHORT- STEP SYNTHESIS OF AMINO ACIDS AND N-HYDROXYAMINO ACIDS FROM AMINES
Catalytic oxidation of secondary amines with hydrogen peroxide followed by treatment with hydrogen cyanide gave α-cyanohydroxylamines (1).Hydrolysis of 1 gave N-hydroxyamino acids (2), which undergo catalytic hydrogenation to give amino acids (3).This is a simple, efficient, and inexpensive method for synthesis of amino acids from amines.
Murahashi, Shun-Ichi,Shiota, Tatsuki
p. 6469 - 6472
(2007/10/02)
A convenient synthesis of a-substituted cyclic α-imino acids
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Yasuo,Suzuki,Yoneda
p. 1931 - 1934
(2007/10/05)
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