- Synthesis, spectral characterization and single crystal X-ray diffraction study of arylazoimidazolium tetraiodobismuthate(III) compounds
-
Eight new organic-inorganic hybrid compounds of 1,3-dialkyl-2-(arylazo) imidazolium, [RaaiR′R″]+, and [Bi4I 16]4- ion are synthesized. The structure has been established by spectral (FT-IR, UV-Vis, 1H NMR) data and the structural confirmation has been done by single crystal X-ray diffraction study in case of [MeaaiMe2+]4[Bi4I 16]4- (where MeaaiMe2+ = 1,3-dimethyl-2-(p-tolylazo)imidazolium). The DFT computation has been used to explain the electronic structure and the electronic spectra of the compounds.
- Mallick,Sarker,Saha,Sinha, Chittaranjan
-
scheme or table
p. 1817 - 1825
(2012/04/17)
-
- Photochromic reaction of a novel room temperature ionic liquid: 2-Phenylazo-1-hexyl-3-methylimidazolium bis(pentafluoroethylsulfonyl)amide
-
We synthesized a new room temperature ionic liquid, [2PA-Hmim][Pf 2N], and characterized the photochromic behavior by absorption spectroscopy. [2PA-Hmim][Pf2N] was found to be a photochromic liquid where solvent itself undergoes photochromic reaction.
- Kawai, Akio,Kawamori, Daiki,Monji, Tomoo,Asaka, Tooru,Akai, Nobuyuki,Shibuya, Kazuhiko
-
supporting information; experimental part
p. 230 - 231
(2010/09/05)
-