Dramatic rate acceleration in titanocene catalyzed epoxide openings: Cofactors and Lewis acid cocatalysis
High synthetic efficiency concerning yield and catalytic turn-over in intermolecular C-C bond forming reactions of radicals derived from epoxides can be achieved by means of hydrogen bonding with cofactors or by Lewis acid cocatalysis.
Catalytic oxidation of alkyl- and cycloalkylcyclanones into lactones
Pilot-plant syntheses of alkyl and cycloalkylcyclanones and their subsequent liquid-phase oxidation into lactones are described. Characteristics of resulting intermediates and target products are reported.
Abbasov,Alimardanov,Suleimanova
p. 621 - 626
(2007/10/03)
A SIMPLE AND SHORT SYNTHESIS OF Z-6-HENEICOSEN-11-ONE AND Z-1,6-HENEICOSEN-11-ONE, THE SEX PHEROMONES OF DOUGLAS-FIR TUSSOCK MOTH
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Reddy, G. Bhaskar,Mitra, R. B.
p. 893 - 900
(2007/10/02)
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