- Synthesis and isomerization of arene oxide metabolites of phenanthrene, triphenylene, dibenz[a,c]anthracene and dibenz[a,h]anthracene
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Dibenz[a,h]anthracene 3,4-oxide 5ARS, synthesised from the enantiopure dibromoMTPA precursor 9ARRS*, was found to have totally racemized and to be accompanied by benz[5,6]anthra[1,2-b]oxepine 11A. Phenanthrene 3,4-oxide 5BRS/su
- Balani,Brannigan,Boyd,Sharma,Hempenstall,Smith
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p. 1091 - 1097
(2007/10/03)
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- A New Synthetic Route to Non-K and Bay Region Arene Oxide Metabolites From cis-Diols
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Arene oxides of naphthalene, quinoline, tripphenylene, benzoppyrene, and dibenzanthracene have been synthesised in enantiopure (1a-c) or racemic form (1d-f), free from oxepine isomers (3d-f) from cis-diol precursors (7a-f) via chloroacetate (9a-f) or dimesylate (13a) intermediates.
- Boyd, Derek R.,Sharma, Narain D.,Agarwal, Rajiv,Kerley, Nuala A.,McMordie, R. Austin S.,et al.
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p. 1693 - 1694
(2007/10/02)
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