- Synthesis of (2E,4Z)-2,4,11-Dodecatrien-1-al, a Degradation Product of Linolenic Acid
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(2E,4Z)-2,4,11-Dodecatrien-1-al (13) has been prepared by using β-bromoallyl alcohol (9) and 1,8-nonadiyne (10) as starting materials. 13 is in agreement with all properties of the natural compound.The synthesis via a Wittig reaction, however, leads to a partial isomerisation of the terminal double bond.
- Bohlmann, Ferdinand,Rotard, Wolfgang
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p. 1216 - 1219
(2007/10/02)
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