- Highly Conductive 2D Metal-Organic Framework Thin Film Fabricated by Liquid-Liquid Interfacial Reaction Using One-Pot-Synthesized Benzenehexathiol
-
Metal-organic frameworks (MOF) are studied extensively in applications like catalysts, gas storage, and sensors due to their various functional groups and structures. Two-dimensional (2D) MOFs such as triphenylene-based materials show excellent charge transport properties, but thin-film fabrication and organic ligand synthesis are difficult. In this work, we synthesize thiol-based organic ligand, benzenehexathiol (BHT), by a simple one-pot reaction. This facile method is safer and faster than conventional synthesis procedure that requires using liquid ammonia as solvent. Two novel 2D MOF materials, Ag3BHT2 and Au3BHT2, are fabricated by coordinating BHT with either silver (Ag) or gold (Au) ions through liquid-liquid interfacial reaction. The Ag3BHT2 thin film reaches a high electrical conductivity of 363 S cm-1, which has potential applications in electronic devices and sensors.
- Chen, Iu-Fan,Lu, Chun-Fu,Su, Wei-Fang
-
p. 15754 - 15762
(2019/01/09)
-
- A persulfurated benzene molecule exhibits outstanding phosphorescence in rigid environments: From computational study to organic nanocrystals and OLED applications
-
A molecule consisting of a hexathio-benzene core and peripheral tolyl substituents exhibits outstanding phosphorescence properties in some environments favoring rigidity, in the solid state and in a solid matrix at 77 K, while no luminescence is recorded
- Bergamini, Giacomo,Fermi, Andrea,Botta, Chiara,Giovanella, Umberto,Di Motta, Simone,Negri, Fabrizia,Peresutti, Romain,Gingras, Marc,Ceroni, Paola
-
p. 2717 - 2724
(2013/05/21)
-
- Benzenehexathiol as a Template Rim for a Golden Wheel: Synthesis and Structure of 6>
-
The reaction of benzenehexathiol, C6(SH)6, with in the presence of triethylamine gave the hexanuclear gold(I) compound 6> whose structure has been determined; the hexagon of the central benzene carbon atoms is surrounded by a hexagon of sulfur atoms, followed by a hexagon of gold atoms and the wheel-like structure is completed by six peripheral phosphine ligands with interlocked aryl groups.
- Yip, Hon Kay,Schier, Annette,Riede, Juergen,Schmidbaur, Hubert
-
p. 2333 - 2334
(2007/10/02)
-
- AN ELECTRON SPIN RESONANCE INVESTIGATION OF THE RADICAL CATIONS FROM POLY(ALKYLTHIO)BENZENES
-
The radical cations of some poly(methylthio)- and poly(isopropylthio)-benzenes have been investigated by e.s.r. spectroscopy.Discrimination between the couplings due to the aryl and alkyl protons, when the assignment is not straightforward, has been made
- Alberti, Angelo,Pedulli, Gian Franco,Tiecco, Marcello,Testaferri, Lorenzo,Tingoli, Marco
-
p. 975 - 980
(2007/10/02)
-
- Reactions of Polychlorobenzenes with Alkanethiol Anions in HMPA. A Simple, High-Yield Synthesis of Poly(alkylthio)benzenes
-
Reactions of the isomeric trichlorobenzenes and tetrachlorobenzenes and of pentachloro- and hexachlorobenzene with an excess of the sodium salt of the isopropanethiol, in HMPA, afforded the products of complete displacement of all the chlorine atoms present in the molecule.Similar substitutions were also obtained with EtSNa.The reactions with MeSNa were in some cases complicated by the competitive nucleophilic attack at the methyl group of the initially formed aryl methyl thioethers which are thus demethylated to afford thiophenols.
- Testaferri, Lorenzo,Tingoli, Marco,Tiecco, Marcello
-
p. 4376 - 4380
(2007/10/02)
-