- REACTIONS OF PENTAFLUOROPHENYLHYDRAZINE AND SOME OF ITS N'-ACYL DERIVATIVES WITH COMPOUNDS CONTAINING A TRICHLOROMETHYL GROUP IN THE PRESENCE OF ALUMUNIUM CHLORIDE
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The reactions of pentafluorophenylhydrazine and also of N'-benzoyl-, N'-pentafluorobenzoyl-, and N'-acetylpentafluorophenylhydrazines and decafluorohydrazobenzene with CCl3R (R=Cl, C6H5, C6F5) in the presence of aluminium chloride were investigated.The main products from the reaction of pentafluorophenylhydrazine with the reagents were N-pentafluorophenylhydrazonodichloromethane and N-pentafluorophenylhydrazonoaryl chlorides.Derivatives of 1,3,4-oxadiazol-2-in-5-one were formed in the reactions of N'-acylpentafluorophenylhydrazines with carbon tetrachloride in the pres ence of aluminium chloride.When heated with carbon tetrachloride and aluminium chloride, decafluorohydrazobenzene disproportionates with the formation of decafluoroazobenzene and pentafluoroaniline.
- Petrova, T. D.,Ryabichev, A. G.,Savchenko, T. I.,Platonov, V. E.,Mamatyuk, V. I.,et al.
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p. 1168 - 1176
(2007/10/02)
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- PERFLUOROPHENYL-CONTAINING VERDAZYL RADICALS
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New formazans, tetrazines, and verdazyl radicals containing perfluorophenyl substituents were obtained on the basis of perfluorophenylhydrazides.The stabilities of mono-, bis-, and tris(perfluorophenyl)verdazyl radicals and their leuco compounds are compa
- Polumbrik, O. M.,Ryabokon', I. G.,Markovskii, L. N.
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p. 882 - 886
(2007/10/02)
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