- Plasmachemical synthesis of the binary hexafluorides of Mo, Os, Ir, Te, and U
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Starting from the respective metal, we have synthesized the binary hexafluorides MF6 of M = Mo, Os, Ir, Te, and U by the use of a remote fluorine plasma source using a mixture of Ar and NF3 as the feed gas. The formation of the binary hexafluorides was confirmed by several different spectroscopic methods including IR, Raman, UV/VIS, and NMR spectroscopy.
- Buchner, M. R.,Chemnitz, T.,Kraus, F.,Petry, W.
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- Industrial fluorine compounds
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Technological research in the area of the industrial fluorine-containing compounds: ozone safe fluorocarbons (freons), fluoro-olefins, compounds with the functional groups, thermoresistant liquids, oils, lubricants, fluorine surfactants and other.
- Barabanov,Maksimov
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p. 1133 - 1141
(2009/12/01)
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- Spectroscopic Studies on the Hexafluorides of Rhenium, Osmium, Iridium, and Platinum isolated in Low-temperature Matrices
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The compounds ReF6, OsF6, IrF6, and PtF6 have been isolated as monomeric species in inert-gas matrices at low temperatures, and characterised by i.r. spectroscopy.Subsequent u.v.-visible studies reveal a complex pattern of electronic absorptions, and a detailed assignment of these in terms of charge transfer, d-d, and intra-configurational transitions is presented.
- Holloway, John H.,Stanger, Gillian,Hope, Eric G.,Levason, William,Ogden, J. Steven
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p. 1341 - 1346
(2007/10/02)
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