Tailored biosynthesis of olefinic medium-chain-length poly[(R)-3-hydroxyalkanoates] in pseudomonas putida GPo1 with improved thermal properties
Mixtures of 5-phenylvalerate, octanoate, and 10-undecenoate were fed to a chemostat culture (dilution rate = 0.1 h-1) of Pseudomonas putida GPo1 under well-defined dual-(C,N)-nutrient limited growth conditions. Five new, tailor-made copolymers
(R)- AND (S)-2-ACETOXY-1,1,2-TRIPHENYLETHANOL - EFFECTIVE SYNTHETIC EQUIVALENTS OF A CHIRAL ACETATE ENOLATE
The enolate 3, easily available by double deprotonation of (R)-2-acetoxy-1,1,2-triphenylethanol (5), adds in a highly stereoselective manner to aldehides.Hydrolysis of the adducts 6/7 affods the acids 2.
Braun, Manfred,Devant, Ralf
p. 5031 - 5034
(2007/10/02)
Stereoselektive Aldolreaktion mit (R)-N-Acetyl-α-phenylglycinol
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Braun, Manfred,Devant, Ralf
p. 802 - 803
(2007/10/02)
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