ORGANOTIN HYDRIDE ADDITIONS TO E- AND Z-TRISUBSTITUTED ETHYLENES.SYNTHESIS OF SOME NEW FUNCTIONALLY SUBSTITUTED ORGANOTIN COMPOUNDS
The syntheses of some new functionally substituted organotin compounds are reported.The results indicate that the additions of tri-n-butyltin and tri-phenyltin hydrides to trisubstituted ethylenes (where one substituent is either a carbomethoxy or a nitrile group) proceed smoothly to give high yields of organotin adducts and that the reactions are stereoselective.Evidence concerning the reversibility of the free radical forming step is presented.
Podesta, J. C.,Chopa, A. B.,Ayala, A.D.
p. 163 - 170
(2007/10/02)
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