- Boron-metal exchange reaction of silylboranes with organometallic reagents: A new route to arylsilyl anions
-
The boron-metal exchange reaction of (arylsilyl)boranes with alkyllithiums, potassium tert-butoxide, and methylmagnesium bromide affords the corresponding silyllithium, silylpotassium, and silylmagnesium compounds, respectively. Especially, the boron-lithium exchange reaction occurs even in hydrocarbon solvents such as toluene and hexane as well as in THF.
- Kawachi, Atsushi,Minamimoto, Takashi,Tamao, Kohei
-
p. 1216 - 1217
(2007/10/03)
-
- Alkylation and acylation of some activated aromatic substrates by organosilicon compounds
-
A method of alkylation and acylation of trinitrobenzene employing the oxidation of anionic ?-complexes generated from organosilicon reagents in the presence of KF/18-crown-6 ether is described.The method enables the introduction of alkyl and acyl substitu
- Artamkina, G. A.,Kovalenko, S. V.,Beletskaya, I. P.,Reutov, O. A.
-
p. 139 - 150
(2007/10/02)
-