Synthesis of a para-quinone macrolactam related to geldanamycin by ring closing metathesis
Model studies conducted with the α,β,γ,δ-unsaturated 3-alkenyl-2,4,5-trimethoxyanilides 11 revealed that a ring closing metathesis (RCM) of these compounds is possible if the ansa chain contains more than 14 atoms. The (Z)-configurated products 12c-e were
Lemarchand, Aude,Bach, Thorsten
p. 9659 - 9673
(2007/10/03)
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