cas 79391-04-1, D-chiro-Inositol, 2-O-.alpha.-D-galactopyranosyl-

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Creation of an α-mannosynthase from a broad glycosidase scaffold
α-Mannosides made easy: Mutation of a family-GH31 α-glucosidase that displays plasticity to alterations at the 2-OH position of donor substrates created an efficient α-mannoside-synthesizing biocatalyst. A simple fluoride donor reagent was used for the synthesis of a range of mono-α-mannosylated conjugates using the α-mannosynthase displaying low (unwanted) oligomerization activity. Copyright
Yamamoto, Keisuke,Davis, Benjamin G.
supporting information; experimental part
p. 7449 - 7453
(2012/09/21)

Synthesis of fagopyritols A1 and B1 from D-chiro-inositol
Fagopyritol A1 (3-O-α-D-galactopyranosyl-D-chiro-inositol) and fagopyritol B1 (2-O-α-D-galactopyranosyl-D-chiro-inositol) have been synthesized by glycosylation of the diequatorial diol 1,4,5,6-tetra-O-benzoyl-D- chiro-inositol, readily obtained from D-ch
Cid, M. Belén,Alfonso, Francisco,Martín-Lomas, Manuel
p. 2303 - 2307
(2007/10/03)

Synthesis of a jojoba bean disaccharide
A synthesis of the disaccharide recently isolated from jojoba beans, 2-O-α-D-galactopyranosyl-D-chiro-inositol, has been achieved. The suitably protected chiro-inositol unit was prepared by an enantiospecific synthesis from L-xylose utilizing SmI2-mediated pinacol coupling as a key step. Copyright (C) 1998 Elsevier Science Ltd.
Kornienko, Alexander,Marnera, Georgia,D'Alarcao, Marc
p. 141 - 144
(2007/10/03)

DERIVATIVES OF ASYMMETRICALLY SUBSTITUTED MYO-INOSITOL. XXXIII. SYNTHESIS OF DIASTEROMERIC MANNOSIDES OF MYO-INOSITOL
Diastereomeric acetylated mannosides of myo-inositol were synthesized by the glycosylation of the racemic acetates of myo-inositol with the ethyl orthoacetate of D-mannose.The synthesized mannosides of myo-inositol can be used for the production of chiral myo-inositol acetates and as intermediates in the synthesis of complex phosphoinositides.
Sibrikov, Yu. I.,Stepanov, A. E.,Shvets, V. I.
p. 470 - 476
(2007/10/02)