- Organophosphorus compounds, 145 - Synthesis and reactivity of a polycyclic, oxa-bridged phosphaalkene
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Thermolysis of 2,3-diphenylindenone 2,3-epoxide (1) in the presence of tert-butylphosphaalkyne (3) proceeds through a regiospecific 1,3-dipolar cycloaddition of the phosphaalkyne to the carbonyl ylide intermediate to furnish the polycyclic phosphaalkene derivative 4. Compound 4 exhibits a remarkable - and for phosphaalkenes unusual - stability: thus, it can be stored for several days and no decomposition can be observed even in the absence of inert gas protection. The phosphaalkene 4 reacts with 1,3-dipoles such as ethyl diazoacetate (8) by formal transfer of its phosphaalkene unit to afford the 1,2,4-diazaphosphole 10. Addition of lithium alkoxides to the phosphaalkene unit of the polycyclic compound 4 occurs diastereoselectively to give the novel phosphinites 13 and 14. In this context it should be mentioned that the choice of the lithium alkoxide has a decisive influence on the preferred formation of one diastereomer of the phosphinite.
- Ruf, Sven G.,Bergstr??er, Uwe,Regitz, Manfred
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- A NEW PHOTO/THERMOCHROMIC SOLID COMPOUND OF THE INDENONE OXIDE FAMILY
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A new strong photochromic solid compound, a 3-ketone of the 2,3-diphenylindenone oxide, has been prepared for first time.The new compound exhibits very strong photochromic and thermochromic phenomena.
- Hadjoudis, E.,Pulima, I.
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