Stereoselective trans-dihydroxylation of terpinen-4-ol: Synthesis of some stereoisomers of p-menthane-1,2,4-triol
A high level of trans-stereoselectivity in the dihydroxylation of the homoallylic alcohol, terpinen-4-ol 1 (R=H) has been achieved. Thus, the enantiomeric triols 2a and 2b were separately synthesized in high yield and with high stereoselectivity by trans-
Constituents of Pyrolytic Products from the Gum Resin of Boswellia carteri Birdw. (Incense "Aden"); III.
1,2,4-Trihydroxy-p-menthane (1) was isolated from the pyrolytic products of incense "Aden" (gum resin of Boswellia carteri Birdw.).The relative and absolute configuration of 1 was established on the basis of spectral and chemical evidences and also confir
Pailer, Matthias,Scheidl, Otto,Gutwillinger, Hans,Klein, Erich,Obermann, Hugo
p. 987 - 1006
(2007/10/02)
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