Cascade radical carbonylations leading to 3-substituted cyclohexanones
Tin radical mediated [5+1]-annulation methods leading to 3-substituted cyclohexanones were investigated. Cyclohexanones having a quaternary center at the 3-position were synthesized in good yields by allyltin-mediated three- and four-component cascade rea
Oxidation of Olefins into α-Phenylseleno Carbonyl Compounds. Highly Regioselective anti-Markownikoff Type Oxidation of Allylic Alcohol Derivatives
By using (C6H5Se)2-t-BuOOH or (C6H5Se)(2-) (C6H5SeO)2O system, oxoselenylation reaction of C=C bonds have been examined with allylic and homoallylic alcohol derivatives, and substituted cyclohexenes, and allyl t-butyldimethylsilyl ethers are found to unde
Shimizu, Makoto,Takeda, Ryo,Kuwajima, Isao
p. 3510 - 3517
(2007/10/02)
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