REACTION OF PROPOSED PHOSPHOROTHIOLATE S-OXIDE INTERMEDIATES WITH ALCOHOLS
S-Oxide 2 is an extremely reactive intermediate.Its phosphorylation vs rearrangement rates, strongly depend upon the nature of the nucleophile.
Segall, Yoffi,Casida, John E.
p. 209 - 212
(2007/10/02)
OXIDATIVE CONVERSION OF PHOSPHOROTHIOLATES TO PHOSPHINYLOXYSULFONATES PROBABLY VIA PHOSPHOROTHIOLATE S-OXIDES
Phosphorothiolate S-oxides and their phosphinyloxysulfenate rearrangement products are probable intermediates in the facile conversion of phosphorothiolates to phosphinyloxysulfonates on peracid oxidation.They may also be intermediates in the biological oxidation of phosphorothiolates.
Segall, Yoffi,Casida, John E.
p. 139 - 142
(2007/10/02)
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