Synthesis, Conformation, and Chirality of Di-O-methylsequirin D, a Biogenetically Novel Metabolite of Sequoia sempervirens
The synthesis of (+/-)-di-O-methylsequirin D (14; R=H) is reported.A Grignard reaction between 3,3-ethylenedioxypropylmagnesium bromide and deoxyanisoin gave the key alcohol (5), which was transformed into (14) by way of the acid (11) and tetralone (12).M
Hatam, Natiq A. R.,Whiting Donald A.
p. 461 - 465
(2007/10/02)
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