COPPER-CATALYZED CONJUGATE ADDITION OF GRIGNARD REAGENTS TO ISOPROPYLIDENE ALKYLIDENEMALONATES
A new method for the synthesis of isopropylidene alkylmalonates involving conjugate addition of Grignard reagents to isopropylidene alkylidene malonates was developed.
Probing persistent intramolecular C-H· · ·X(X = O, S, Br, Cl, and F) bonding in solution using benzyl meldrum's acid derivatives
Persistent intramolecular interactions between acidic C-H hydrogens and a variety of acceptors (X) (X = O, S, Br, Cl, and F) in solution were probed by 1H NMR experiments, using 5-benzyl Meldrum's acid derivatives. To bring about formation of i
Fillion, Eric,Wilsily, Ashraf,Fishlock, Dan
supporting information; experimental part
p. 1259 - 1267
(2009/06/28)
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