Structure and Stereochemistry of the Dehydrobromination of some β-Bromo Ketones Derived from Alkyl Phenyl Ketones and Benzaldehyde
The aldol reaction of alkyl phenyl ketones with benzaldehyde in the presence of hydrogen bromide affords diastereomeric β-bromo ketones under thermodynamic control.Thus, from propiophenone (8a) two diastereomeres 9a are obtained in a 67 : 33 ratio, while
Quast, Helmut,Mueller, Bodo,Peters, Karl,Schnering, Hans Georg von
p. 1525 - 1546
(2007/10/02)
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