- Total synthesis of zizaane sesquiterpenes: (-)-khusimone, (+)-zizanoic acid, and (-)-epizizanoic acid
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Three sesquiterpenes of the zizaane family, khusimone (1), epizizanoic acid (3), and zizanoic acid (2) have been synthesized in optically active form from the ammonium salt of (-)-l-10-camphorsulfonic acid in sixteen, nineteen, and twenty steps respectively.
- Liu, Hsing-Jang,Chan, Wing Hong
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p. 1081 - 1091
(2007/10/02)
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- INSECT REPELLENTS FROM VETIVER OIL. I. ZIZANAL AND EPIZIZANAL
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On the basis of spectral data and partial synthesis, structures 1 and 2 are established for zizanal and epizizanal, two new insect-repelling aldehydes isolated from Javanese vetiver oil ( Vetiveria zizanoides).
- Jain, Subhash C.,Nowicki, Stephen,Eisner, Thomas,Meinwald, Jerrold
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p. 4639 - 4642
(2007/10/02)
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