- FREE-RADICAL TRANSFORMATIONS OF 2-ALKOXY-1,3-DIOXOLANES IN POLYHALOGENOALKANES
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The free-radical transformations of 2-ethoxy-1,3-dioxolane and 2-hexyloxy-1,3-dioxolane in bromoform and chloroform were investigated.The products from these transformations are alkyl 2-halogenoalkyl carbonates, 2-halogenoethyl formates, the corresponding cyclic and linear carbonates, aldehydes, and halogenoalkanes.A scheme of homolytic transormations is proposed for 2-alkoxy-1,3-dioxolanes in polyhalogenoalkanes.
- Rol'nik, L. Z.,Kalashnikov, S. M.,Pastushenko, E. V.,Zlot-skii, S. S.,Rakhmankulov, D. L.
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p. 1296 - 1299
(2007/10/02)
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