Anodic coupling of carboxylic acids to electron-rich double bonds: A surprising non-Kolbe pathway to lactones
Carboxylic acids have been electro-oxidatively coupled to electron-rich olefins to form lactones. Kolbe decarboxylation does not appear to be a significant competing pathway. Experimental results indicate that oxidation occurs at the olefin and that the reaction proceeds through a radical cation intermediate.
Perkins, Robert J.,Xu, Hai-Chao,Campbell, John M.,Moeller, Kevin D.
supporting information
p. 1630 - 1636
(2013/10/22)
Compounds and methods for fluorescent labeling
Compounds useful in the fluorescent labeling of biological materials are provided along with methods for their use and preparation.
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Page/Page column 33
(2008/06/13)
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