1-Alkylthio-3-aryloxypropan-2-ols: Synthesis and enantiomer separation by lipase-catalyzed transesterification
The optically active (R)- and (S)-1-alkylthio-3-aryloxypropan-2-ols were prepared in the reaction of the appropriate arylglycidyl ethers and alkyl thiols followed by lipase-catalyzed transesterification. The effect of aryl and alkyl substituents, the enzyme preparation as well as the reaction conditions have been compared in terms of enantiomeric excess of the obtained acetate and the unreacted alcohol.
Wielechowska, Monika,Plenkiewicz, Jan
p. 3203 - 3210
(2007/10/03)
SYNTHESIS AND INVESTIGATION OF 1-BUTYLTHIOMETHYL-2-ARYLOXYETHYL ARYLCARBAMATES AND THIOCARBAMATES AS ADDITIVES FOR LUBRICATING OILS
1-Butylthio-3-aryloxy-2-propanols were synthesized by the reaction of 1-chloro-3-aryloxy-2-propanols with 1-butanethiol in an alkaline medium.In condensation with aromatic isocyanates and isothiocyanates they form 1-butylthiomethyl-2-aryloxyethyl arylcarb
Gasanov, V. S.,Alekperov, R. K.
p. 83 - 86
(2007/10/02)
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