- Photodecomposition of some para-substituted 2-pyrazolylphenyl azides. Substituents affect the phenylnitrene S-T gap more than the barrier to ring expansion
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A series of para-substituted (H, Me, Cl, F, CF3, OMe, NMe2) phenyl azides bearing a dimethylpyrazolyl group in position 2 allowing intramolecular trapping of singlet nitrene have been photolyzed at both 295 and 90 K in ethanol. For t
- Albini, Angelo,Bettinetti, Gianfranco,Minoli, Giovanna
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p. 3104 - 3113
(2007/10/03)
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