- The structures of some iminium salts. Crystal structures and 13C NMR studies of 3-aryl-2-propenylideniminium salts
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The X-ray crystal structures of E-N,N-dimethyl-3-phenyl-2-propenylideniminium perchlorate, 1 and E-N,N-dimethyl-3-(p-methoxyphenyl)-2-propenylideniminium perchlorate, 2, have been determined.E-N,N-dimethyl-3-phenyl-2-propenylideniminium perchlorate, (C11H
- Childs, Ronald F.,Dickie, Brian D.,Faggiani, Romolo,Fyfe, Colin A.,Lock, Colin J. L.,Wasylishen, Roderick E.
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- PHOTOCHEMICAL AND THERMAL STEREOMUTATIONS OF 3-ARYL-2-PROPENYLIDENIMINIUM SALTS.
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Salts in trifluoroacetic acid solution undergo efficient cis/trans isomerization about the C equals C bonds on irradiation. These reactions involve singlet excited states of the iminium salts. Photoisomerization also occurs about the C equals N bonds of s
- Childs,Dickie
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p. 5041 - 5046
(2007/10/02)
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