- Synthesis of Ketones and Methanols Containing Pyridinyl and N-Methylimidazolyl Groups
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N-Methylimidazolyllithium reacts with N-methylimidazole-2-carboxaldehyde to form bis(N-methylimidazol-2-yl)methanol, and with the esters ethyl N-methylimidazole-2-carboxylate and ethyl pyridine-2-carboxylate to give bis(N-methylimidazol-2-yl)methanone, (mim)2CO, and (N-methylimidazol-2-yl)(pyridin-2-yl)methanone, (Py)(mim)CO, respectively.The ketones react with N-methylimidazolyllithium to give tris(N-methylimidazol-2-yl)methanol, (mim)3COH, and bis(N-methylimidazol-2-yl)(pyridin-2-yl)methanol, (Py)(mim)2COH, respectively.
- Canty, Allan J.,George, Edwin E.,Lee, Christopher V.
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p. 415 - 418
(2007/10/02)
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