cas 863971-63-5, Carbonylhydrido[6-(di-t-butylphosphinomethylene)-2-(N,N-diethylaminomethyl)-1,6-dihydropyridine]ruthenium(II), min. 98% | Articles data ｜lookchem

Welcome to LookChem.com Sign In|Join Free

Article Database

Home > CAS Article list >
863971-63-5

Articles about 863971-63-5Total 3 be found

Article title
Article abstract
Author
Journal number and time
Download

Catalytic CO2 hydrogenation to formate by a ruthenium pincer complex
This paper reports the hydrogenation of carbon dioxide to formate catalyzed by the Ru pincer complex Ru(PNN)CO(H) (PNN = 6-(di-tert- butylphosphinomethylene)-2-(N,N-diethylaminomethyl)-1,6-dihydropyridine). Stoichiometric studies are presented that support the feasibility of the individual steps in a proposed catalytic cycle for this transformation. The influence of base and solvent on catalyst performance is explored. Overall, under optimized conditions (using diglyme as the solvent and potassium carbonate as the base) up to 23,000 turnovers of formate and a turnover frequency of up to 2,200 h-1 can be achieved.
Huff, Chelsea A.,Sanford, Melanie S.
p. 2412 - 2416
(2013/10/22)

Reversible carbon-carbon bond formation between carbonyl compounds and a ruthenium pincer complex
This communication describes the reversible reaction of a ruthenium pincer complex with a variety of carbonyl compounds. Both NMR spectroscopic and X-ray crystallographic characterization of isomeric carbonyl adducts are reported, and the equilibrium constants for carbonyl binding have been determined.
Huff, Chelsea A.,Kampf, Jeff W.,Sanford, Melanie S.
supporting information
p. 7147 - 7149
(2013/08/23)

Facile conversion of alcohols into esters and dihydrogen catalyzed by new ruthenium complexes
An efficient, environmentally benign method for the preparation of esters from alcohols under mild, neutral conditions without the need for carboxylic acid derivatives and condensing agents was developed. Catalyst design, based on new Ru(II) hydrido carbonyl complexes incorporating electron-rich PNP and PNN ligands has resulted in the novel complex (I) which is an outstanding catalyst for the dehydrogenation of primary alcohols to esters and H2 under neutral conditions. Copyright
Zhang, Jing,Leitus, Gregory,Ben-David, Yehoshoa,Milstein, David
p. 10840 - 10841
(2007/10/03)

More Articles about upstream products of 863971-63-5

Chemical Properties

Storage Temp.:under inert gas (nitrogen or Argon) at 2-8°C
Sensitive: air sensitive, store cold
PSA: 21.76000
LogP: 4.64480

Show more

Global suppliers and manufacturers of 863971-63-5total 10 suppliers on LookChem

Company Name
Business Type
Min Order
FOB Price
Main Products
Contact

Henan Sinotech Import&Export Corporation
Business Type:Other
Min Order:1 Kilogram
FOB Price:USD $ 1.0-1.0 / Kilogram
Main Products:20
Country:

BOC Sciences
Business Type:Trading Company
Min Order:No Data
FOB Price:No Data
Main Products:41
Country:

Antimex Chemical Limied
Business Type:Lab/Research institutions
Min Order:No Data
FOB Price:No Data
Main Products:163
Country:

ZHEJIANG JIUZHOU CHEM CO.,LTD
Business Type:Trading Company
Min Order:No Data
FOB Price:No Data
Main Products:27
Country:

Amadis Chemical Co., Ltd.
Business Type:Lab/Research institutions
Min Order:10 Milligram
FOB Price:No Data
Main Products:1
Country:

Shanghai Hanhong Scientific Co.,Ltd.
Business Type:Trading Company
Min Order:No Data
FOB Price:No Data
Main Products:1
Country:

Chemical Technology Co.,LTD
Business Type:Other
Min Order:No Data
FOB Price:No Data
Main Products:1
Country:

Cerametek Materials（ShenZhen）Co., Ltd.
Business Type:Other
Min Order:No Data
FOB Price:No Data
Main Products:1
Country:

Strem Chemicals, Inc.
Business Type:Other
Min Order:No Data
FOB Price:No Data
Main Products:1
Country:

Finetech Industry Limited
Business Type:Trading Company
Min Order:No Data
FOB Price:No Data
Main Products:1
Country:

Post a RFQ

Cas No.:

Product Name:

Quantity:

Email:

Company name:

Valid Period:

Detailed Requirements:

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

1

What can I do for you?
Get Best Price

Get Best Price for 863971-63-5

About us - Payment - Contact us - Links - Help Center - Disclaimer
SiteMap | Manufacturers | VIP Product | Suppliers | CAS | New CAS | Cas Database | Article Data | Chemical Catalog | Product Name

©2008 LookChem.com,License:ICP NO.:Zhejiang16009103 complaints:service@lookchem.com
[Hangzhou]86-571-87562588,87562561,87562573 Our Legal adviser: Lawyer