Synthesis, structure and reactivity of organogold compounds of relevance to homogeneous gold catalysis
Organogold(I) phosphane complexes were prepared, their structure was investigated and their reactivity in reactions with Michael acceptors, sources of electrophilic halogens and protons were investigated.
Hashmi, A. Stephen K.,Ramamurthi, Tanuja Dondeti,Rominger, Frank
p. 592 - 597
(2009/06/05)
Organogold(I) complexes: Synthesis, X-ray crystal structures and aurophilicity
The synthesis of RAuPPh3 (R = aryl) from ClAuPPh3 and Grignard RM reagents (M = Li or MgX) is described. New (vinylphenyl)gold(I) and other arylgold(I) complexes were characterized by 1H, 13C, 31P, s